Synthesis, X-Ray Structural Determination and Coordination Chemistry of 4’-Ferrocenyl-2,2’ : 6’,2”- Terpyridine
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Terence "Terry" Nile, Professor (Creator)
- Jerome "Jerry" Walsh, Professor and Associate Head (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: 4'-Ferroceny1-2,2' : 6',2"-terpyridine(Fctrpy) has been prepared from ferrocene carboxaldehyde and 2-acetylpyridine. A single crystal X-ray structure analysis indicates typical bond distances and angles with nearly coplanar aromatic rings. The angle between the cyclopentadienyl ring of the ferrocene moiety and the central pyridyl ring of the terpyridine is 19.2° Ruthenium complexes, Ru(Fctrpy)22+ and Ru(trpy) (Fctrpy)2+ (trpy = 2,2' : 6',2"-terpyridine) have been prepared and characterized electrochemically and spectrophotometrically.
Synthesis, X-Ray Structural Determination and Coordination Chemistry of 4’-Ferrocenyl-2,2’ : 6’,2”- Terpyridine
PDF (Portable Document Format)
395 KB
Created on 4/14/2011
Views: 1407
Additional Information
- Publication
- Polyhedron, 12, 2891.
- Language: English
- Date: 1993
- Keywords
- Structure analysis, bond distances, aromatic rings, ruthenium complexes