Jerome "Jerry" Walsh

**Expertise: Inorganic Chemistry, Chemical Education **Education: B.S., University of Wisconsin, 1970--M.S. University of Wisconsin, 1975--Ph.D., University of Wisconsin, 1977--Postdoctoral Fellow, University of North Carolina, 1977-79

There are 8 included publications by Jerome "Jerry" Walsh :

TitleDateViewsBrief Description
Acceleration of Ligand Exchange by Coordinated Nitrate in Polypyridyl Ruthenium Complexes 1989 3356 The rate of substitution of L by a chloride ion or acetonitrile in cis-[Ru(bpy)2 (L)(X)]+ (X = NO3; L = pyridine, acetonitrile ; bpy = 2,2'-bipyridine) in low polarity solvents, is greatly enhanced over the rates obse...
Gas-phase Nuclear Magnetic Resonance Spectroscopic Study of the Molecular Structure of Beryllium Borohydride, Be(BH<sub>4</sub>)<sub>2</sub> 1977 1867 Gas-phase and solution n.m.r. spectral studies of beryllium borohydride, Be(BH4)2, indicate that it contains magnetically equivalent BH4 groups which undergo rapid internal hydrogen exchange; previously postulated...
Preparation and X-ray crystal structure study of a polypyridyl ruthenium(II) complex containing a dehydrodithizone ligand 1998 2739 Coordination of 2,3-diphenyltetrazolium-5-thiolate (tet) to an Ru(trpy)(bpy)(OH2)2+ (trpy=2,2':6',2"-terpyridine; bpy=2,2'-bipyridine) centre resulted in the formation of [Ru(trpy)(bpy)(tet)](ClO4)2. Single-crystal X-...
Preparation and X-ray Structure of 2-Tetrahydroborato-2-berylla-<i>nido</i>-hexaborane(11) : Insertion of Beryllium into a Borane Cage 1976 1570 Reaction of beryllium borohydride with 1-chloropentaborane(9) results in insertion of a beryllium atom into the borane cage to give 8-tetrahydroborato-2-berylla-nido-hexaborane(11).
A ruthenium complex with 1,5-di- phenyl-3-thiocarbazone (dithizone) as monodentate ligands: bis(2,2'- bipyridyl-<i>&#x03BA</i><sup>2</sup>N,N')bis(dithizonato-<i>&#x03BA</i>S)- ruthenium(II) 2003 2212 The title compound, [Ru(C13H11N4S)2(C15H8N2)2], has C2 symmetry, with bidentate 2,2'-bipyridyl ligands dictating a cis geometry around ...
Structural Chemistry of Necessarily Distorted Bis(Bipyridine) Complexes. The Crystal Structure of the Trans-[Bis(2,2'-Bipyridine)Bis(Triphenul-Phosphine)Ruthenium(II)] and Trans-[Bis(4,4'-Dimethyl-2,2'-Bipyridine)Bis(Pyridine)Ruthenium(ii)] Cations 1982 2463 The cation trans-[Ru(bpy)2(PPh3)2]2+ and trans-[Ru(Me2bpy2)2(py)2]2+ both contain bipyridine ligands which are distorted because of the c...
Synthesis, X-Ray Structural Determination and Coordination Chemistry of 4'-Ferrocenyl-2,2':6',2''-terpyridine 1993 2123 4'-Ferrocenyl-2,2' : 6',2"-terpyridine(Fctrpy) has been prepared from ferrocene carboxaldehyde and 2-acetylpyridine. A single crystal X-ray structure analysis indicates typical bond distances and angles with nearly coplanar aromatic rings. The angle ...
Synthesis, X-Ray Structural Determination and Coordination Chemistry of 4’-Ferrocenyl-2,2’ : 6’,2”- Terpyridine 1993 1407 4'-Ferroceny1-2,2' : 6',2"-terpyridine(Fctrpy) has been prepared from ferrocene carboxaldehyde and 2-acetylpyridine. A single crystal X-ray structure analysis indicates typical bond distances and angles with nearly coplanar aromatic rings. The angle ...