A ruthenium complex with 1,5-di- phenyl-3-thiocarbazone (dithizone) as monodentate ligands: bis(2,2'- bipyridyl-<i>κ</i><sup>2</sup>N,N')bis(dithizonato-<i>κ</i>S)- ruthenium(II)
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Jerome "Jerry" Walsh, Professor and Associate Head (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: The title compound, [Ru(C13H11N4S)2(C15H8N2)2], has C2
symmetry, with bidentate 2,2'-bipyridyl ligands dictating a cis
geometry around the RuII center. The monodentate S-bonded
dithizone ligands are almost planar, except for one of the
phenyl rings, which is twisted by 34.2 (4)° from the N/N/C(S)/
N/N plane. The RuÐS bond length is 2.4140 (13) Å, and the
RuÐN bond lengths are 2.048 (4) and 2.074 (4) Å.
A ruthenium complex with 1,5-di- phenyl-3-thiocarbazone (dithizone) as monodentate ligands: bis(2,2'- bipyridyl-<i>κ</i><sup>2</sup>N,N')bis(dithizonato-<i>κ</i>S)- ruthenium(II)
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Created on 3/10/2011
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Additional Information
- Publication
- Acta Crystallographica Section C. Crystal Structure Communications (2003). C59, 268-270
- Language: English
- Date: 2003
- Keywords
- Crystals, Chemical compounds, Molecular structure