Protodecarboxylation of ß-keto-acrylates and synthesis of isomaleimides by dehydration of maleamic acids using methanesulfonyl chloride
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Elvis C. McFee (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
- Advisor
- Mitchell Croatt
Abstract: The development of unique reaction conditions for the protodecarboxylation of P-keto-acrylic acids is described. This expansion on previous work ameliorates the requirement of added water, affording a homogeneous reaction system. As an unexpected discovery in substrate preparation, the synthesis of isomaleimides using methanesulfonyl chloride as a dehydrating agent is also presented.
Protodecarboxylation of ß-keto-acrylates and synthesis of isomaleimides by dehydration of maleamic acids using methanesulfonyl chloride
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Created on 5/1/2021
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Additional Information
- Publication
- Thesis
- Language: English
- Date: 2021
- Keywords
- Carboxylic Acid, Catalysis, Decarboxylation, Isomaleimide, Palladium, Protodecarboxylation
- Subjects
- Decarboxylation
- Palladium catalysts
- Acrylates