Investigating the Influence of Various Migratory Allyl Ethers on the Regioselectivity of the Aromatic Claisen Rearrangement
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Logan E. Brown (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
- Advisor
- Mitchell P. Croatt
Abstract: We report an investigation into the regioselectivity of the aromatic Claisen rearrangement within a novel asymmetric substrate that possesses an internal base meta to the aryl allyl ether position. We utilize various migratory aryl allyl ethers and aryl propargyl ethers to study how steric bulk influences the regioselectivity. Our results show that steric bulk does influence the regioselectivity of the aromatic Claisen rearrangement.
Investigating the Influence of Various Migratory Allyl Ethers on the Regioselectivity of the Aromatic Claisen Rearrangement
PDF (Portable Document Format)
482 KB
Created on 8/9/2023
Views: 144
Additional Information
- Publication
- Honors Project
- Language: English
- Date: 2023
- Keywords
- aromatic Claisen rearrangement, aryl allyl ether, benzopyran, regioselectivity