Rhodium(I)-Catalyzed [2+2], [2+2+2], and [2+2+2+2] Cycloadditions of Dienes or Alkynes with a Bis-ene
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Mitchell Croatt, Assistant Professor (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: A novel metal-catalyzed, all-alkene [2+2+2] cycloaddition reaction involving a strained and conformationally restricted bis-ene and a diene is reported. Modification of the catalyst leads to competition with a diene-ene [2+2] reaction, and when an alkyne was used in place of the diene, [2+2+2] and [2+2+2+2] cycloaddition reactions occurred involving the bis-ene and 1 or 2 equiv of the alkyne.
Rhodium(I)-Catalyzed [2+2], [2+2+2], and [2+2+2+2] Cycloadditions of Dienes or Alkynes with a Bis-ene
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Created on 1/15/2019
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Additional Information
- Publication
- Organometallics 2009, 28, 5841-5844
- Language: English
- Date: 2009
- Keywords
- cycloaddition reactions