| Title | Date | Views | Brief Description |
|---|
| Protonation state of the bridging Ligand in the resting state of cytochrome c oxidase: investigations of synthetic Heme/Copper models |
2021 |
97 |
Inspiration for our research stems from biological redox processes performed by metalloenzymes. Heme-containing enzymes are able to perform oxidation and reduction reactions, such as in cytochrome P450 and cytochrome c oxidase (CcO). The focus of the... |
| Dioxygen Reactivity of Bioinspired Copper(I) and Copper(I)/Manganese(II)-Porphyrin Systems |
2022 |
147 |
Transition metal-dioxygen (O2) interactions are of great importance in biological and chemical transformations involving dioxygen binding, activation, or reduction. In this work, the independent O2 reactivity of a series of bioinspired copper(I) comp... |
| Synthetic oxo-bridged manganese(porphyrin)-copper complexes derived from dioxygen chemistry |
2024 |
32 |
This report investigates the expanded library of manganese/copper oxo-bridged complexes derived from dioxygen chemistry. Our group previously reported a Mn/Cu system, [(tmpa)CuII-O-MnIII(TPP)]+, formed from O2 chemistry at ambient conditions, where [... |