Synthesis of Novel Substituted Cyclopentadienes and Their Early Transition Metal Complexes
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Terence "Terry" Nile, Professor (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: Synthesis of two substituted cyclopentadienes, 1,3-bis(1-methylcyclohexyl) cyclopentadiene, Cp'H and [2-methyl-2-(2-pyridyl)ethyl]cyclopentadiene, Cp"H from fulvene intermediates is reported. These are readily converted to their early transition metal complexes Cp'W(CO)3Me, Cp"Mo(CO)3Me, Cp"W(CO)3Me and [Cp"Ti(O)Cl · CH2Cl2]2. The X-ray crystal structure of the titanium compound shows that the nitrogen of the pyridine cyclopentadienyl substituent is coordinated to the titanium.
Synthesis of Novel Substituted Cyclopentadienes and Their Early Transition Metal Complexes
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Created on 4/14/2011
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Additional Information
- Publication
- Polyhedron, 8, 1804 (1989).
- Language: English
- Date: 1989
- Keywords
- synthesis, cyclopentadienes, titanium compound