Hydrosilylation of 1-Pentyne by Triethylsilane Catalyzed by Phosphine-Rhodium Complexes
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Terence "Terry" Nile, Professor (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: The hydrosilylation of 1-pentyne by triethylsilane has been investigated using rhodium catalysts, formed by displacement of cyclooctene from dichlorotetrakis(cyclooctene)dirhodium(I) by various molar ratios of phosphines. The results are interpreted in terms of isomerization of an intermediate vinylrhodium complex.
Hydrosilylation of 1-Pentyne by Triethylsilane Catalyzed by Phosphine-Rhodium Complexes
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Created on 4/14/2011
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Additional Information
- Publication
- Journal of Organometallic Chemistry, 206, 299 (1981)
- Language: English
- Date: 1981
- Keywords
- hydrosilylation, catalysts