Rhodium Phosphite Clusters as Hydrosilylation Catalysts
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Terence "Terry" Nile, Professor (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: The activity of rhodium phosphite complexes as catalyst precursors for hydrosilylation reactions has been investigated. These are found to be active for a wide variety of organic substrates. Both hydride clusters, [RhH[P(OR3)}2]n and chloride dimers, [RhCl{P(OR)3}2]2 (R = methyl or o-tolyl) were evaluated. The hydrosilylation of 1-hexyne by triethylsilane was investigated as a function of phosphite:rhodium ratio and also with various phosphites as ligand.
Rhodium Phosphite Clusters as Hydrosilylation Catalysts
PDF (Portable Document Format)
416 KB
Created on 4/19/2011
Views: 2570
Additional Information
- Publication
- Journal of Molecular Catalysis, 42(1), 91 (1987).
- Language: English
- Date: 1987
- Keywords
- Rhodium phosphate, complexes, catalyst precursors, hydrosilylation reactions, organic substrates, hydride clusters, phosphites