Hypervalent Iodonium Alkynyl Triflate Generated Phenylcyanocarbene and Its Reactivity with Aromatic Systems
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Mohammed Al-Huniti, Research Scientist (Creator)
- Mitchell Croatt, Assistant Professor (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: Phenylcyanocarbene was generated by the reaction of azide with a hypervalent iodonium alkynyl triflate and reacted in situ with 21 different carbocyclic and heterocyclic aromatic compounds. These reactions led to more complex products that frequently underwent subsequent rearrangements. The reactivity was further explored in a mechanistic study to ascertain the chemoselectivity and stereospecificity.
Hypervalent Iodonium Alkynyl Triflate Generated Phenylcyanocarbene and Its Reactivity with Aromatic Systems
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Created on 2/19/2019
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Additional Information
- Publication
- Journal of Organic Chemistry 2017, 82, 11772-11780
- Language: English
- Date: 2017
- Keywords
- reactions, phenylcyanocarbene, chemoselectivity, stereospecificity