Hydrosilylation of 1-Pentyne by Triethylsilane Catalyzed by Phosphine-Rhodium Complexes

UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
Terence "Terry" Nile, Professor (Creator)
The University of North Carolina at Greensboro (UNCG )
Web Site: http://library.uncg.edu/

Abstract: The hydrosilylation of 1-pentyne by triethylsilane has been investigated using rhodium catalysts, formed by displacement of cyclooctene from dichlorotetrakis(cyclooctene)dirhodium(I) by various molar ratios of phosphines. The results are interpreted in terms of isomerization of an intermediate vinylrhodium complex.

Additional Information

Journal of Organometallic Chemistry, 206, 299 (1981)
Language: English
Date: 1981
hydrosilylation, catalysts

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