Synthesis, X-Ray Structural Determination and Coordination Chemistry of 4'-Ferrocenyl-2,2':6',2''-terpyridine

UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
Terence "Terry" Nile, Professor (Creator)
Jerome "Jerry" Walsh, Professor and Associate Head (Creator)
Institution
The University of North Carolina at Greensboro (UNCG )
Web Site: http://library.uncg.edu/

Abstract: 4'-Ferrocenyl-2,2' : 6',2"-terpyridine(Fctrpy) has been prepared from ferrocene carboxaldehyde and 2-acetylpyridine. A single crystal X-ray structure analysis indicates typical bond distances and angles with nearly coplanar aromatic rings. The angle between the cyclopentadienyl ring of the ferrocene moiety and the central pyridyl ring of the terpyridine is 19.2° Ruthenium complexes, Ru(Fctrpy)22+ and Ru(trpy) (Fctrpy)2+ (trpy = 2,2' : 6',2"-terpyridine) have been prepared and characterized electrochemically and spectrophotometrically.

Additional Information

Publication
Polyhedron, 12(23), 2891 (1993).
Language: English
Date: 1993
Keywords
Chemistry, Crystal, Ruthenium complex