Transannular effects in cage compounds : the alcohol-ketal exchange reaction of 3-methoxy-4-oxahexacyclo [5.4.1.0. 0?. 0?. 0?. ]? dodecane
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- William Francis Smith (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
- Advisor
- James Barborak
Abstract: The transannular effects in a homologous series of dimethoxy cage alochols were studied by use of physical methods such as infrared and nmr spectra. It was shown that a pronounced transannular effect occurred in these cage compounds which manifested itself as an increasingly stronger hydrogen bond between the hydroxyl proton and the endo-methoxyl oxygen as the number of carbon atoms increases in the C bridge. The occurrence of transannular effects in these compounds was also supported by an intramolecular alcohol-ketal exchange reaction and molecular mechanics calculations.
Transannular effects in cage compounds : the alcohol-ketal exchange reaction of 3-methoxy-4-oxahexacyclo [5.4.1.0. 0?. 0?. 0?. ]? dodecane
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Created on 1/1/1974
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Additional Information
- Publication
- Thesis
- Language: English
- Date: 1974
- Subjects
- Alcohols
- Organic compounds