Boronate macrocycle formation using boron-Lewis base dative bonds and boronic acid-diol condensation reactions
- WCU Author/Contributor (non-WCU co-authors, if there are any, appear on document)
- Natalie Rose Rizzo (Creator)
- Institution
- Western Carolina University (WCU )
- Web Site: http://library.wcu.edu/
- Advisor
- William Kwochka
Abstract: Synthesis of boronate ester compounds via condensation reactions using either an amine or an amine N-oxide coupled with a boronic acid. Synthesis of boronate ester compounds using quinoline isomers coupled with 2, 3-dihydroxynaphthalene was also attempted. These compounds form B-N dative bonds, and potentially form macrocycles capable of trapping a guest molecule in the cavity. The exact sizes of the complexes are unknown at this time. Characterization of these compounds was performed by 1H NMR, FT-IR, mass spectroscopy, and 13C NMR.
Boronate macrocycle formation using boron-Lewis base dative bonds and boronic acid-diol condensation reactions
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Created on 7/1/2013
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Additional Information
- Publication
- Thesis
- Language: English
- Date: 2013
- Keywords
- Boronate Esters, Dative Bonding, Macrocycles, Nitrogen-Boron dative bonds
- Subjects
- Boron compounds -- Synthesis
- Macrocyclic compounds -- Synthesis
- Boron compounds -- Properties
- Macrocyclic compounds -- Properties