|(2)rotaxanes as reagents for (3)rotaxane sythesis [i.e. synthesis]
||It was our hope to demonstrate that fairly simple systems such as a rotaxane can itself be used as a reagent to synthesize even larger systems such a rotaxane. This modular type approach offers several advantages over alternative methods. The [...
|Displacement reactions and fluorescence studies of boroxine amine complexes
||The Boron atom has seen an increase in usefulness over the last half
century due in part to the unique properties of boron that allow for dative binding.
Aspects of the boron-nitrogen bond were examined through both displacement
reactions, which w...
|Synthesis and characterization of boron-nitrogen datively bonded supramolecular assemblies and rotors
||The synthesis of three adducts of ferrocene boroxine (C10H9Fe)3B3O3 with dative bonds
to amines (pyridine, 4-picoline, 4-aminomethyl pyridine, and p-bromoaniline), as well as
to two diamines (4,4-bipyridine and 1,4-diazabicyclo[2.2.2]octane) to for...