A ruthenium complex with 1,5-di- phenyl-3-thiocarbazone (dithizone) as monodentate ligands: bis(2,2'- bipyridyl-<i>&#x03BA</i><sup>2</sup>N,N')bis(dithizonato-<i>&#x03BA</i>S)- ruthenium(II)

UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
Jerome "Jerry" Walsh, Professor and Associate Head (Creator)
The University of North Carolina at Greensboro (UNCG )
Web Site: http://library.uncg.edu/

Abstract: The title compound, [Ru(C13H11N4S)2(C15H8N2)2], has C2 symmetry, with bidentate 2,2'-bipyridyl ligands dictating a cis geometry around the RuII center. The monodentate S-bonded dithizone ligands are almost planar, except for one of the phenyl rings, which is twisted by 34.2 (4)° from the N/N/C(S)/ N/N plane. The RuÐS bond length is 2.4140 (13) Å, and the RuÐN bond lengths are 2.048 (4) and 2.074 (4) Å.

Additional Information

Acta Crystallographica Section C. Crystal Structure Communications (2003). C59, 268-270
Language: English
Date: 2003
Crystals, Chemical compounds, Molecular structure

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