Organic Peroxide Assisted Transition Metal Hydrosilylation Catalysis
- UNCG Author/Contributor (non-UNCG co-authors, if there are any, appear on document)
- Terence "Terry" Nile, Professor (Creator)
- Institution
- The University of North Carolina at Greensboro (UNCG )
- Web Site: http://library.uncg.edu/
Abstract: The catalytic activity of rhodium complexes for the hydrosilylation of substrates such as alkenes, 1,3-dienes, 1-alkynes, or ketones, is enhanced by the addition of organic oxidizing agents, such as t-butyl hydroperoxide, hydrogen peroxide, or m-chloroperbenzoic acid. Similar enhancement is found for the Group VIA hexacarbonyls in the hydrosilylation of 1,3-dienes.
Organic Peroxide Assisted Transition Metal Hydrosilylation Catalysis
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Created on 4/19/2011
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Additional Information
- Publication
- Transition Metal Chemistry, 8(6), 365 (1983).
- Language: English
- Date: 1983
- Keywords
- Catalytic activity, rhodium complexes, hydrosilylation, oxidizing agents